DNAPL Removal from a Heterogeneous Alluvial Aquifer by Surfactant- Enhanced Aquifer Remediation     

John T. Londergan  Hans W. Meinardus  Paul E. Manner  Richard E. Jackson  Chris L. Brown  Varadarajan Dwarakanath  Gary A. Pope  Jon S. Ginn  Sam Taffinder 《Ground Water Monitoring & Remediation》2001,21(3):71-81

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Structure proof and significance of stereoisomeric 28,30-bisnorhopanes in petroleum and petroleum source rocks     

J.Michael Moldowan  Wolfgang K. Seifert  Edward Arnold  Jon Clardy 《Geochimica et cosmochimica acta》1984,48(8):1651-1661

Two C₂₈H₄₈-pentacyclic triterpanes were isolated from Monterey shale. X-ray crystallography of a crystal containing both compounds proved their structures as 17β,18α,21α(H)-28,30-bisnorhopane and 17β,18α,21β(H)-28,30-bisnorhopane. Several differences are found between 28,30-bisnorhopanes and the regular hopanes. Unlike the regular hopane epimers, for practical purposes the three epimeric 28,30-bisnorhopanes [17α,21β(H)-, 17β,21α(H)-, and 17β,21β(H)-]cannot be distinguished by their mass spectra. Special conditions are needed to separate them by gas chromatography. The diagenetically first-formed epimer is thought to be 17α,21β(H)- because it predominates in immature shales. The order of thermodynamic stability is 17β,2lα(H) < > 17α,21β(H) > 17β,21β(H), and all three epimers are present in petroleum. 25,28,30-Trisnorhopanes can be analyzed in similar fashion and are found to have similar thermodynamic characteristics. The percent of the ring D/E cis epimer of 28,30-bisnorhopane and/or 25,28,30-trisnorhopane is a useful maturation parameter similar to the 20S/20R sterane ratio. Evidence indicates 25-demethylation of 28,30-bisnorhopane to 25,28,30-trisnorhopane during advanced stages of biodegradation. Hence, percent ring $\text{D}\text{E}$cis 25,28,30-trisnorhopane has an application to maturation assessment in heavily biodegraded oils.  相似文献   

A. Programmable device for simulation of tidal flux     

Mark L. Gleason  Jon R. DiMarco  Joseph C. Zieman 《Estuaries and Coasts》1981,4(3):220-222

An apparatus is described which permits precise, versatile control of simulated tidal flux in laboratory microcosms. A key component of the system, a programmable electronic control unit, can closely imitate any natural tidal function and is readily adaptable to other experimental applications that utilize timed switching capability. The programmable control unit is also cheaper and easier to operate than computer-based systems.  相似文献   

Complex Archean lower crustal structure revealed by COCORP crustal reflection profiling in the Wind River Range,Wyoming     

Scott B. Smithson  Jon A. Brewer  S. Kaufman  J.E. Oliver  R.L. Zawislak 《Earth and Planetary Science Letters》1980,46(2):295-305

A COCORP deep crustal reflection profile across the Wind River uplift crosses exposed Archean rocks and resolves an unusual complex deep crustal structure at a depth of 24–31 km in an area where depth relations in Precambrian rocks can be inferred. The different levels of exposure across the beveled plunge of the Wind River uplift reveal supracrustal rocks at shallower levels with migmatites and pyroxene granulites at deeper levels. For the first time, deep crustal structure from reflection profiling may be interpreted in terms of exposed basement geology. A folded, multilayered deep structure shown by relfection data resembles multiply folded pyroxene granulite interlayered with granitic gneiss exposed in the central Wind River uplift; isoclinal folding is suggested in the folded layered seismic structure. Earlier seismic reflection studies suggested a simpler lower crust. These data indicate that lower crustal structure may have a complexity similar to deeply eroded Precambrian granulite-facies rocks. If this seismic feature represents folded metamorphic rocks, it seems unlikely that this Archean crust could have been thickened by underplating after 2.7 b.y. B.P. and the crust would have to be at least 30 km thich when this structure was formed.  相似文献   

The impact of freshwater discharges on the ocean circulation in the Skagerrak/northern North Sea area. Part II: energy analysis     

Jon Albretsen 《Ocean Dynamics》2007,57(4-5):287-304

We perform eddy-permitting to eddy-resolving simulations of the Skagerrak/northern North Sea with a terrain-following numerical ocean model. We demonstrate that realistic representations of freshwater input are not required when the focus is on modelling mesoscale structures such as meanders and eddies. To arrive at this conclusion, we analyze the results using a recently developed energy diagnostic scheme to study the sensitivity to realistic representations of the lateral freshwater flux provided to the area from the Baltic Sea and by the major rivers. The scheme is suitable for analysis of growth of instabilities, and it has four basic instability processes prominent. We recognize both horizontal and vertical shear instabilities. There are two processes where average potential energy is converted to eddy kinetic energy, and they are related to the mean gradient in surface elevation and the mean lateral density gradient, respectively. The latter process is known as frontal instability. We demonstrate that the change in the eddy kinetic energy field is small, despite the large variations in the hydrographic properties from experiment to experiment. Moreover, generation of eddy activity appears at the same locations and with approximately the same strength regardless of actual representations of freshwater input. Furthermore, we find that vertical shear instability dominates the energy conversion processes in the Norwegian Coastal Current. Finally, we find that the areas off the northwest coast of Denmark recognized with enhanced eddy kinetic energy level is not caused by instability processes but eddy–eddy interaction rooted in variations in the sea level.  相似文献   

Guest Editorial     

Michael Wiedenbeck  Jon Woodhead 《Geostandards and Geoanalytical Research》2007,31(4):299-299

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Results from a Multi-disciplinary Sedimentary Pilot Study of Tectonic Lake Iznik (NW Turkey) – Geochemistry and Paleolimnology of the Recent Past     

Sven O. Franz  Lorenz Schwark  Cathrin Brüchmann  Burkhard Scharf  Ralf Klingel  Jon D. Van Alstine  Namık Çagatay  Umut B. Ülgen 《Journal of Paleolimnology》2006,35(4):715-736

A limnogeological reconnaissance study was carried out on Lake Iznik, located in the southeast of the Marmara region of Turkey, involving a seismic survey and collection of short sediment cores. This lake is located on the middle branch of the North Anatolian Fault Zone (NAFZ), a transform plate boundary between the Eurasian and Anatolian Plates. It is, therefore, tectonically active and offers an opportunity to investigate the interplay of sedimentary and seismo-tectonic processes, as well as climate change and human impact in the region. Short cores of the three sub-basins, maximum length of 35.5 cm, recovered non-laminated, blackish clays and silts with varying amounts of biogenic and minerogenic (allochthonous, autochthonous) material, which documented almost the last 80 years of deposition and environmental history. High sedimentation rates in the deeper core sections are accompanied by changes in land use (conversion of woodland to farmland) in the northern areas of Lake Iznik, which caused the deposition of more weathered material (high K/Na ratios) and higher contents of Mn in the lake. A tendency towards eutrophic conditions within the last 20 years is indicated by high nutrient content (N, TOC, P), decreasing C/N-ratios, and characteristic diatom and cladoceran associations. Also increased pollution is revealed by higher Pb, Cu, and Zn contents and increased supply of human and animal faeces (high coprostanol content) during the last two decades. But simultaneous lower sedimentation rates towards the core tops complicate the reconstruction of recent and past eutrophication and pollution states of Lake Iznik. This requires an extension of the pilot study and deeper sediment cores, to recover non-anthropogenic influenced sediment levels.  相似文献   

GGR Critical Review of Analytical Developments in 2004–2005     

Janet M. Hergt  L. Paul Bédard  Etienne Deloule  Klaus Peter Jochum  Kathryn L. Linge  Paul J. Sylvester  Matthias Willbold  Jon D. Woodhead 《Geostandards and Geoanalytical Research》2006,30(3):141-142

In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.  相似文献   

Holocene history of lacustrine and marsh sediments in a dune-blocked drainage, Southwestern Nebraska Sand Hills, U.S.A.   总被引：1，自引：0，他引：1  

Jon P. Mason  James B. Swinehart  David B. Loope 《Journal of Paleolimnology》1997,17(1):67-83

As many as 2500 interdune lakes lie within the Nebraska Sand Hills, a 50000 km stabilized sand sea. The few published data on cores from these lakes indicate they are typically underlain by less than two m of Holocene lacustrine sediments. However, three lakes in the southwestern Sand Hills, Swan, Blue, and Crescent, contain anomalously thick marsh (peat) and lacustrine (gyttja) sediments. Swan Lake basin contains as much as 8 m of peat, which was deposited between about 9000 and 3300 years ago. This peat is conformably overlain by as much as 10.5 m of gyttja. The sediment record in Blue lake, which is 3 km downgradient from Swan lake, dates back to only about 6000 years ago. Less than two m of peat, which was deposited from 6000 to 5000 years ago, is overlain by 12 m of gyttja deposited in the last 4300 years. Crescent Lake basin, one km downgradient from Blue Lake, has a similar sediment history except for a lack of known peat deposits. Recently, a 8-km long segment of a paleovalley was documented running beneath the three lakes and connecting to the head of Blue Creek Valley. Blockage of this paleovalley by dune sand during two arid intervals, one shortly before 10500 yr BP and one in the mid-Holocene, has resulted in a 25 m rise in the regional water table. This made possible the deposition of organic-rich sediment in all three lakes. Although these lakes, especially Swan, would seem ideal places to look for a nearly complete record of Holocene climatic fluctuations, the paleoclimatic record is confounded by the effect dune dams have on the water table. In Swan Lake, the abrupt conversion from marsh to lacustrine deposition 3300 years ago does not simply record the change to a wetter regional climate; it reflects the complex local hydrologic changes surrounding the emplacement and sealing of dune dams, as well as regional climate.  相似文献   

Core formation and the oxidation state of the Earth: Additional constraints from Nb, V and Cr partitioning   总被引：1，自引：0，他引：1  

Bernard J. Wood  Jon Wade 《Geochimica et cosmochimica acta》2008,72(5):1415-1426

We have combined metal-silicate partitioning data from the literature with new experimental results at 1.5-8 GPa and 1480-2000 °C to parameterize the effects of pressure, temperature and composition on the partitioning of V, Cr and Nb between liquid Fe metal (with low S and C content) and silicate melt.Using information from the steelmaking literature to correct for interactions in the metal phase, we find that, for peridotitic silicate melts, metal-silicate partition coefficients are given by: